High-performance
phosphorescent organic light-emitting devices (PhOLEDs) at high luminance
are still a remaining problem that needs to be solved, especially
blue PhOLEDs. Here, 5-(5-9H-carbazol-9-yl)pyridin-2-yl)-8-(9H-carbazol-9-yl)-5H-pyrido[3,2-b]indole (p2PCB2CZ) with excellent characteristics as a
host is designed to realize a novel host–guest system without
hole trapping effect in blue PhOLEDs. The device in which p2PCB2CZ
and bis(3,5-difluoro-2-(2-pyridyl)phenyl-(2-carboxypyridyl)iridium(III)
(FIrpic) is used as host and guest, respectively, is proposed to improve
the performances of blue PhOLEDs at high luminance, especially at
ultrahigh luminance (>30000 cd/m2). The maximum external
quantum efficiency (EQE) of this type of blue PhOLEDs is 19.2%, while
the maximum EQE of the reference blue PhOLEDs is 18.7%. Nevertheless,
the p2PCB2CZ-based devices exhibit significant advantages at high
luminance, because its EQE still attains to 10.8% even when the luminance
increases to 30000 cd/m2, which is 1.67 times that of the
reference device. From measurements based on steady-state and time-resolved
spectroscopies, the reduction of triplet-polaron quenching in p2PCB2CZ-based
devices is proved to be the main reason for improving the performances
of blue PhOLEDs at high luminance.