a b s t r a c t a r t i c l e i n f oMagnesium (Mg) and Strontium (Sr) doped Calcium fluoride nanocrystals were synthesized by co-precipitation method. The cubic structure of the samples was confirmed by Powder X-ray diffraction. The average crystallite size of Mg doped samples was found to be~25 nm whereas in Sr doped one it was~35 nm. The morphological features revealed that the nanocrystals were agglomerated, crispy and porous. The as-prepared samples showed the presence of hydroxyl groups. The optical absorption spectrum of as-prepared Mg doped samples showed a strong absorption band peaked at~233 nm whereas the Sr doped one showed a prominent absorption peak at 248 nm. A strong PL emission was observed at~300 nm in Mg doped samples. However, the Sr doped samples showed two prominent emissions at~345 and 615 nm.