Low-Valent Titanium Induced Reductive Coupling of Nitriles with Nitro Compounds

Zhou, Longhu; Zhang, Yongmin

doi:10.1080/00397919808004430

Cited by 24 publications

(9 citation statements)

References 27 publications

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“…In [13,14] the prevalence of tautomer B was stated but we thought this statement insuffi ciently confi rmed. The conversion of tautomer B into tautomer A was performed using a catalyst of a complex structure [14].…”

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confidence: 90%

“…IR spectrum, ν, cm -1 : 3480 (NH 2 ), 1620 (C=N). 1 H NMR spectrum, δ, ppm: 6.02 s (2H, NH 2 ), 6.86-7.98 m (10H, Ph) 13. C NMR spectrum, δ, ppm: 122.05-136.33 (Ph), 154.14 (N-C=N).…”

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confidence: 99%

“…The structure of N-arylbenzamidines Va-Vj was proved by 1 H, 13 C NMR, IR, and UV spectra. The IR spectra of amidines in question contain two absorption bands in the region 1610-1620 (C=N) and 3410-3500 (NH 2 ) cm -1 .…”

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confidence: 99%

“…The obtained aroylamidines hydrochlorides IIIa-IIId are solid colorless or light-yellow crystalline substances, well soluble in water and ethanol. Their structure was proved by 1 H, 13 The most characteristic signals in the 1 H NMR spectra of the solutions of compounds IIIa-IIId in DMSO-d 6 are the peaks of the protons of the groups C=NH 2 + , NH 2 (9.0-9.8 ppm) and of the aromatic ring (7.8-8.8 ppm). In the IR spectra of aroylamidines hydrochlorides IIIa-IIId an absorption band appears at 1675-1680 cm -1 corresponding to the stretching vibrations of the C=N bond.…”

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confidence: 99%

“…H,13 C, 15 N-HSQC were registered on a spectrometer Bruker AM-400 (400 MHz) from solutions of compounds…”

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confidence: 99%

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Synthesis and structure of aroylamidines and N-arylbenzamidines hydrochlorides

et al. 2012

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Aroylamidines can be obtained as salts in a reaction of the corresponding arylcarbonitriles with anhydrous ethanol in the presence of dry HCl followed by treating intermediate imidoesters with alcoholic solution of ammonia. N-Arylbenzamidines are obtained by reacting benzonitrile with arylamines in the presence of AlCl 3 . The structure of arylamines and the reaction conditions signifi cantly affect the yield of the target product, and sometimes the very possibility of its preparation.

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confidence: 90%

“…IR spectrum, ν, cm -1 : 3480 (NH 2 ), 1620 (C=N). 1 H NMR spectrum, δ, ppm: 6.02 s (2H, NH 2 ), 6.86-7.98 m (10H, Ph) 13. C NMR spectrum, δ, ppm: 122.05-136.33 (Ph), 154.14 (N-C=N).…”

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confidence: 99%

mentioning

confidence: 99%

mentioning

confidence: 99%

“…H,13 C, 15 N-HSQC were registered on a spectrometer Bruker AM-400 (400 MHz) from solutions of compounds…”

mentioning

confidence: 99%

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