Abstract-Four chlorite polytypes of Bailey and Brown (1962) have been identified by X-ray diffraction in clay-size chlorites of soils, sediments, and sedimentary rocks: (1) lib, the polytype of common metamorphic and igneous chlorites; (2) lb(/3 = 90~ (3) lbffi = 97~ (4) la. An additional stacking arrangement, iba, is defined herein as disordered chlorite which lacks an hOl diffraction band in the 2-4-2.5 A region.Most type-I chlorites are authigenic, as demonstrated by thin-section petrography. Type-1 chlorites form during diagenesis, or less commonly during halmyrolysis, at temperatures and pressures less than those of low-grade metamorphism. A type-I crystallization sequence is proposed, from least to most stable: lbd ---> lb(/3 = 97 ~ --~ Ib(/3 = 90~ Conditions of low-grade metamorphism usually are necessary to cause conversion of lb(/3 = 90 ~ to lib, the most stable and common polytype. Chemical composition has little or no influence upon polytype relative stabilities; temperature is much more important.Sediment source areas with high relief, abundant rainfall, cold climate, and which contain libchlorite-bearing metamorphic rocks, may yield essentially unweathered 1 l b chlorite to sites of deposition. Thus, clay-size lib chlorite in unmetamorphosed sedimentary rocks can be interpreted as detrital. Caution is required, however, because 11 b may be able to form authigenically at submetamorphic temperatures, because it is the most stable polytype. Petrographic evidence is useful in such cases.Chlorite polytypism as a geothermometer can be applied to several geologic problems: (1) the authigenic versus detrital origin of clay minerals in sedimentary rocks, particularly in graywacke matrix; (2) the recognition of diagenetic facies or gradients, areally and stratigraphically, within given geologic provinces; (3) the detection of hydrothermal and incipient metamorphic effects. Chlorite polytypism merits general application as an interpretive tool. INTRODUCTION CLAY minerals, like most other minerals, record the physical and chemical conditions under which they formed. Clay minerals, once formed, are sensitive to subsequent changes in the physical and chemical environments of their host rocks. Fine grain size, large surface area, structural and compositional complexities make this so. Clay minerals, therefore, can provide a decipherable record of rock history, embracing the processes of weathering, transportation, deposition, diagenesis, and low-grade metamorphism. Clay-size chlorite is a common layer silicate in sedimentary rocks, sediments, and some soils. The main objective of this paper is to show how chlorite polytypism is related to chlorite occurrence, stability, composition, and parent material. From this, chlorite potytypism can be used to interpret origin of clay minerals in sediments and sedimentary rocks.