SummaryThe exhaust gas of a LPG fuelled engine is drawn through two bubblers in series in an ice bath, and filled with saturated 2,4-dinitrophenylhydrazine in 2M HCI. After heating the derivatives are extracted with toluene-cyclohexane and l gl samples injected "on-column" on a OVl capillary Column. Using an FID the lower limit of detection is 15-18pg for formaldehyde (about 8--10 ppbv for a 161 exhaust sample). Taking the blank into account, the limit is about 40ppbv.The exhaust gases of a LPG-fuelled engine contain formaldehyde, acetaldehyde, propionaldehyde, acrolein and acetone. Carbonyl compounds of more than 3 C-atoms were not found in detectable amounts. The engine was fund under stoichiometric, lean and rich air/fuel conditions. Under rich conditions the concentrations of the aldehydes were: formaldehyde 2.8ppm, acetaldehyde 1.3 ppm, propionaldehyde 0.06 ppm, acrolein 0.03 ppm, acetone 0.17ppm; under stoichiometric conditions: 4.5, 1.6, 0.10, 0.03 and 0.18ppm respectively; under lean conditions 17.0, 2.9, 0.13, 0.07 and O.27ppm respectively. These figures demonstrate the necessity of measuring aldehydes in exhaust gases of LPG-fuelled engines.lean misfire limit of an LPG-fuelled engine extends well beyond the limit with gasoline and can be used to achieve low emission levels of regulated pollutants (hydrocarbons, oxides of nitrogen, carbon monoxide). However, the problem of obtaining a suitable LPG engine with proper carburation and ignition design, hinders full utilization of LPG as a "clean" motor fuel. Moreover, the use of LPG as a motor fuel depends largely on the fuel tax policy of the various countries.