2007
DOI: 10.4314/bcse.v21i2.21196
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<b>RUTHENIUM(III) DETERMINATION BY KINETIC-CATALYTIC METHOD USING THE NILE BLUE-ACIDIC CHLORITE REACTION</b>

Abstract: The mechanism of the Ru(III) catalysed oxidation of Nile blue (3-amino-7diethylamino-8,9-benzo-2-phenoxazine chloride, NB +) by acidic chlorite were investigated by kinetic approach and using the stopped flow technique at 633 nm. The catalysed reaction had a first-order dependence on the concentrations of NB + , H + , ClO 2 and catalyst. The pertinent mechanism, consistent with the experimental results is proposed. Based on the high sensitivity and selectivity of the reaction to the presence of Ru(III), using … Show more

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“…The rate constants and activation parameters for the oxidation have been determined. 132 In the oxidation of alkanethiols to disulfides with chloramine-T (CAT), in alkaline solution, the proposed reactive species are hypochlorous acid and TsNCl − anion. A correlation of reaction rate with Taft's dual substituent parameter equation yielded ρ * = −5.28 and δ = −2.0, indicating the rate-enhancing effect of electron-donating substituents.…”
Section: Halogensmentioning
confidence: 99%
“…The rate constants and activation parameters for the oxidation have been determined. 132 In the oxidation of alkanethiols to disulfides with chloramine-T (CAT), in alkaline solution, the proposed reactive species are hypochlorous acid and TsNCl − anion. A correlation of reaction rate with Taft's dual substituent parameter equation yielded ρ * = −5.28 and δ = −2.0, indicating the rate-enhancing effect of electron-donating substituents.…”
Section: Halogensmentioning
confidence: 99%