2002
DOI: 10.1117/12.475173
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<title>Characterization of the electromechanical properties of ionomeric polymer-metal composite (IPMC)</title>

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Cited by 57 publications
(41 citation statements)
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“…Coupled electrical-chemical-mechanical response of IPMCs depends on the structure of the backbone ionic polymer, the morphology and conductivity of the metal electrodes, the nature of the cations, and the level of hydration (or other solvent uptake) 6,35 and the chemical structure of the ionomer backbone. 39 The speed and magnitude of this actuation towards the anode depends on the type of solvent.…”
Section: Effect Of Different Cationsmentioning
confidence: 99%
“…Coupled electrical-chemical-mechanical response of IPMCs depends on the structure of the backbone ionic polymer, the morphology and conductivity of the metal electrodes, the nature of the cations, and the level of hydration (or other solvent uptake) 6,35 and the chemical structure of the ionomer backbone. 39 The speed and magnitude of this actuation towards the anode depends on the type of solvent.…”
Section: Effect Of Different Cationsmentioning
confidence: 99%
“…It was applied a step voltage of U=0.5, 1.0, 1.5, 2.0 and 2.5 during a time long enough (100 s) to occur the back relaxation. Voltages higher than 2.5V were avoided due to the possible hydrolysis of the water and some damages to the platinum electrodes 8 . The parameters K´1, K´2, τ 1 and τ 2 of the Equation 2 were extracted by the experimental data using a non-linear curve-fitting tool based on the Levenberg-Marquardt algorithm in MATLAB.…”
Section: Methodsmentioning
confidence: 99%
“…The PTFE backbone form small crystallites distributed through an amorphous matrix responsible to the hydrophobic phase and have an important role in the mechanical and thermal properties of Nafion [4][5][6] . In response to a step voltage applied on the electrodes of a hydrated Nafion based IPMC sample, the membrane realizes a fast bending movement toward the anode followed by a slow reverse movement toward the cathode 1,2,[7][8][9] . This reverse bending movement is usuallu called by back relaxation 3 .…”
Section: Modelmentioning
confidence: 99%
“…These models can be broadly classified into three major categories: black-box model, grey-box model and physics model. Blackbox models are used for empirically deriving relation between the input and the output [3][4][5][6]. These models are based on system identification and curve fitting and are useful for understanding the macroscopic electromechanical behaviour of IPMC [7].…”
Section: Introductionmentioning
confidence: 99%