Physics Innovations Inc. has developed polarization-sensitive imaging sensors with high-spatial resolution. In this paper we describe methods where video frames are captured and processed into images of the target's temperature distribution and the target's three dimensional shape and orientation. We demonstrate that the two angles describing surface orientation can be determined for every point on a target. For all targets in the field of view, their geometric shapes and temperatures can be determined simultaneously. With high-speed signal processing, high-resolution polarimetric data can be captured and displayed in real time and at video frequency.Conventional methods for passively detecting and identifying targets often rely on sensing the intensity of infrared light reflected or emitted by objects. A fundamental problem associated with sensing the intensity is that intensity gives one parameter while the orientation of surface elements has two degrees of freedom. Physics Innovations Inc. is developing a thermal imaging technique for determining surface orientation where, in each image pixel, two parameters are sensed simultaneously. The two parameters, percent of polarization P and angle of the plane of polarization are directly related to the two angles of surface orientation. Although thermal infrared intensity images of terrestrial scenes have low contrast, images of P and often have high contrast for different surface orientations. This high contrast should facilitate image segmentation and classification of objects.Polarization also gives useful information about the surface properties of the object. Man-made objects have unnaturally smooth surfaces, leading to radiation with greater polarization. Natural backgrounds such as grass, trees, dirt, and sand emit and reflect radiation that is less polarized.Researchers have recognized the potential usefulness of imaging polarization data for target detection and recognition. However, wide-spread use of polarization data in the infrared has not occurred, probably because polarization-sensitive imaging methods have been slow, bulky, and subject to object misregistration. Physics Innovations Inc. is developing polarization-sensitive imaging sensors which are compact, portable, and, for some applications, can be retrofitted into existing optical imaging systems. This paper describes the operation of polarization-sensitive thermal imaging sensors which are capable of simultaneously capturing intensity and polarization data without misregistration and in real time. The results show that three-dimensional information, in addition to temperature distribution, can be captured and displayed in real time and at near video frequency. These results also show that polarization data provides useful contrast, enough to distinguish man-made objects from backgrounds and to distinguish different surface orientations.