Luminescent Cd^II metal–organic frameworks based on isoniazid using a mixed ligand approach

Abstract

Herein we report the syntheses and characterization of two novel CdII-based metal–organic frameworks (MOFs) with the formulae: [{Cd(INH)(hpdia)}·3H2O]α (Cd-MOF-1) and [{Cd(INH)(bdc)}·DMF]α (Cd-MOF-2) (INH = isoniazid, hpdia = 5-(4-hydroxyphenylazo)isophthalic acid), H2bdc...

Coordination Polymers as a Functional Material for the Selective Molecular Recognition of Nitroaromatics and ipso‐Hydroxylation of Arylboronic Acids

“…Taking into account the importance of coordination compounds of d 10 metal ions and π-electron-rich organic ligand towards the useful luminescent properties. [38][39][40][41][42][43][44] The UV-vis absorption spectrum of 1, 2 as well as ligand L (Ref. [5]) were recorded in DMSO at room temperature and the concerned plots are depicted in Figure S8.…”

Thiophene-Functionalized Cadmium(II)-Based Metal–Organic Frameworks for CO2 Adsorption with Gate-Opening Effect, Separation, and Catalytic Conversion

“…The Cd−O and Cd−N bond lengths are in the range of 2.334(10)−2.522(10) and 2.147(9)−2.313(5) Å, respectively, and these values are comparable with the reported values. 56 The detailed bond lengths and angles are reported in Table S8 (Supporting Information).…”

Pillared MOFs: structure and ring opening polymerization of cyclic esters

“…One of the most thoroughly investigated systems is mixed-ligand systems using benzene-1,4-dicarboxylic acid (H 2 BDC) with a variety of neutral linkers. [6][7][8][9][10] When compared with the previously reported 2-D structures, 11 those resulting from the use of the related ligand 5-aminoisophthalic acid (H 2 -5-AIP, Chart 1 left) showed very similar binding modes, but with significant differences in the orientation of the 5-AIP units, resulting in 2-D sheets that can be further linked in to 3-D frameworks by the intercalation of linear dipyridyls. In a similar study, Jin et al created lanthanide-based MOFs with mixed carboxylates of H 2 -5-AIP and oxalic acid.…”

“…One of the most thoroughly investigated systems is mixed-ligand systems using benzene-1,4-dicarboxylic acid (H 2 BDC) with a variety of neutral linkers. 6–10…”