Luminescent MOFs for selective sensing of Ag⁺ and other ions (Fe(iii) and Cr(vi)) in aqueous solution

Abstract

Two new title MOFs, [Zn(BTA)2]n(MOF-1), [Zn3(BTA)2(5-tbuip)2]n(MOF-2) (BTA=1H-Benzotriazole, 5-tbuip=5-tert-Butylisophthalcc Acid) have been synthesized by solvothermal method. The structures of two complexes have been determined by single-crystal X-ray diffraction analysis and further...

Three multi-responsive luminescent Zn-CPs for the detection of antibiotics/cations/anions in aqueous media

“…[15][16][17] Cr(VI) ions with strong oxidation and carcinogenic properties are considered hazardous substances listed by the World Health Organization leading to cancer, malformations, and genetic mutations. [18][19][20] Several analytical techniques including atomic fluorescence spectrometry (AFS), atomic absorption spectrometry (AAS), X-ray fluorescence (XRF) spectrometry, and inductively coupled plasma mass spectrometry (ICP-MS) have been developed for the detection of environmental pollutants. 21 However, their complexity and high cost are limitations to these techniques.…”

Three new Zn(ii) coordination polymers for highly selective and sensitive detection of Fe3+

“…The bond length distances of Zn-O range from 1.924 to 2.279 Å, which is consistent with the normal distances of the Zn-O bond length. [46][47][48][49][50][51][52][53] Zn1 and Zn2 are bridged by the O6 atom, while Zn2 and Zn3 are linked with O3W. So a trinuclear metal cluster composed of Zn(II) ions (Zn1, Zn2 and Zn3) is obtained (Fig.…”

Two-Dimensional Lanthanide Metal–Organic Frameworks as a Platform for Sensing Pollutant and Nitrophenols Reduction

“…Therefore, designing and synthesizing a method for rapid detection of antibiotics in wastewater is critical but challenging. , Similarly, the detection of inorganic ions in wastewater is of great significance for the protection of ecological balance and animal and plant health. CrO 4 2– /Cr 2 O 7 2– ion, as a highly water-soluble oxyanion, has terrible toxicity and carcinogenicity after being discharged into the environment, leading a potential threat to humans and aquatic life in trace levels in water. − Therefore, the detection of Cr­(VI) ions is highly imperative for the protection of the human health and environment. − …”