Luminescent properties of CaMgSi2O6-based phosphors co-doped with different rare earth ions

Preparation and spectral analysis of a new Tb3+-doped CaO–MgO–SiO2 glass ceramics

“…properties, machinability, high uniformity and stability [12,13]. In numerous glass ceramic systems, silicate system is one of the best choices for its good thermal stability and physicochemical property, the previous reports have shown the outstanding luminescence properties and long afterglow phenomenon of Ca 2 MgSi 2 O 7 :Eu 2+ , Dy 3+ [14], CaMgSi 2 O 6 :Eu 2+ , Dy 3+ [15]. So the further investigation of rare earth-doped silicate glass ceramic has potential application on the optical devices.…”

Photoluminescence of Eu2+-doped CaMgSi2xO6+2x (1.00⩽x⩽1.20) phosphors in UV–VUV region

“…3, respectively. We ascribe the excitation 200-450 nm to the crystal-field splitting of Eu 2+ 4f 7 ( 8 S 7/2 )-4f 6 5d( 7 F J ) transition according to the assignment in other Eu 2+ -doped systems [10,12]. The emission spectrum shows the maximum intensity at about l=453 nm, which is due to the 4f-5d transition of Eu 2+ .…”

“…CaMgSi 2 O 6 doped with rare-earth and transition-metal ion phosphors have been studied by some researchers [8][9][10][11][12]. Among these studies, Kunimoto et al have prepared blue-emitting phosphor CaMgSi 2 O 6 :Eu 2+ with Si-rich mixture and it was concluded that the PL intensity under vacuum ultraviolet (VUV) excitation was enhanced with excess SiO 2 [11].…”

Studies on the photoluminescence behavior of rare earth (Ce, Sm Eu, Dy, Tb) activated calcium magnesium silicate phosphors

“…In the diopside, position M 1 is occupied by Mg and position M 2 is occupied by Ca. On the other hand, CMS is a good bio-compatible materials with high bioactivity, high thermal stability, and the sintered diopside form seems to form bonds with living bone tissues more rapidly than apatite [17,18] ) was added as flux. The small amounts of flux, improve the phosphors luminescent intensity, reduce the phosphor synthetic temperature, improve the phosphor synthetic quality and increase the production rate.…”