Random coincidences of nuclear events can be one of the main background sources in low-temperature calorimetric experiments looking for neutrinoless doublebeta decay, especially in those searches based on scintillating bolometers embedding the promising double-beta candidate 100 Mo, because of the relatively short half-life of the twoneutrino double-beta decay of this nucleus. We show in this work that randomly coinciding events of the two-neutrino double-beta decay of 100 Mo in enriched Li 100 2 MoO 4 detectors can be effectively discriminated by pulse-shape analysis in the light channel if the scintillating bolometer is provided with a Neganov-Luke light detector, which can improve the signal-to-noise ratio by a large factor, assumed here at the level of ∼750 on the basis of preliminary experimental results obtained with these devices. The achieved pile-up rejection efficiency results in a very low contribution, of the order of ∼6 × 10 −5 counts/(keV·kg·y), to the background counting rate in the region of interest for a large volume (∼90 cm 3 ) Li 100 2 MoO 4 detector. This background level is very encouraging in view of a possible use of the Li 100 2 MoO 4 solution for a bolometric tonne-scale next-generation experiment as that proposed in the CUPID project.