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SATO, Yoshio; Nakai, Toshihiro; TASUMI, Kenji

doi:10.1246/nikkashi.1979.941

NIPPON KAGAKU KAISHI

1979

DOI: 10.1246/nikkashi.1979.941

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Yoshio SATO¹,

Toshihiro Nakai²,

Kenji TASUMI³

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2008

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Permeation Behavior of Methanesulfonic Acid and Tin Methanesulfonate Solutions in Diffusion Dialysis and Electrodialysis with Ion-exchange Membranes

Takahashi¹,

Kikuchi²

2008

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Membrane permeation characteristics of methanesulfonic acid and tin methanesulfonate were examined in diffusion dialysis and electrodialysis with ion-exchange membranes. In the diffusion dialysis experiments, the methanesulfonic acid permeated through an anion-exchange membrane, but did not permeated through a cation-exchange membrane. The apparent diffusivities of methanesulfonic acid through the anion-exchange membrane were determined with the flux of methanesulfonic acid and the concentration difference between the compartments. The values were the same order of hydrochloric acid permeation in the anion-exchange membrane. In the experiment of electrodialysis for tin methanesulfonate solution, methanesulfonic acid moved to the anode-side strip compartment through the anionexchange membrane, but tin ion moved to the cathode-side strip compartment through the cation-exchange membrane. These fluxes were almost proportional to the current density, and the flux of tin ion agreed with the theoretical value corresponding to that di-charged ion permeates at the transport number equal to unity.

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Permeation Behavior of Methanesulfonic Acid and Tin Methanesulfonate Solutions in Diffusion Dialysis and Electrodialysis with Ion-exchange Membranes

Takahashi¹,

Kikuchi²

2008

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show abstract

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Cited by 1 publication

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Permeation Behavior of Methanesulfonic Acid and Tin Methanesulfonate Solutions in Diffusion Dialysis and Electrodialysis with Ion-exchange Membranes

Permeation Behavior of Methanesulfonic Acid and Tin Methanesulfonate Solutions in Diffusion Dialysis and Electrodialysis with Ion-exchange Membranes

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