Deep
eutectic solvents have emerged as promising alternatives to
traditional lubricants due to their ease of preparation, low cost,
low/no pollution, reproducibility, and unique antifriction and antiwear
performance. Herein, green sorbitol-based deep eutectic solvents are
successfully synthesized using d-sorbitol and quaternary
ammonium salts as hydrogen bond donors and acceptors, respectively,
through a simple heating and stirring method. The synthesized sorbitol-based
deep eutectic solvents exhibit good thermostability, high viscosity,
and favorable wettability on the steel surface. Notably, tribological
tests demonstrated that the sorbitol-based deep eutectic solvents
displayed outstanding antiwear and friction-reducing properties and
were observed to achieve nearly wearless behavior on the steel surface
under high contact pressure (2.16 GPa). X-ray photoelectron spectroscopy,
scanning electron microscopy, and high-resolution transmission electron
microscopy revealed that complex tribofilms were formed because of
the tribochemical reactions and physical adsorption of deep eutectic
solvents on steel substrates, resulting in outstanding tribological
properties. These results demonstrate that the as-synthesized sorbitol-based
deep eutectic solvents are promising candidates for green and sustainable
lubricating materials with eminent tribological properties. Furthermore,
the present work may provide guidance and reference for the development
of green and high-performance deep eutectic solvent-based lubricating
materials.