Magnesium and Calcium Isotopic Geochemistry of Silica‐Undersaturated Alkaline Basalts: Applications for Tracing Recycled Carbon

Abstract

Carbon plays important roles in the evolution of the atmosphere and biosphere, and geochemical differentiation in Earth's interior. Most subducted C is recycled to the deep mantle and returns to the surface by degassing from erupted basalts and associated fluids. The Mg–Ca isotopic systems have been widely used in tracing recycled C. However, the idea that these geochemical proxies truly reflect the deep C cycle has been challenged. Here we present whole‐rock geochemical and Mg–Ca isotopic compositions of Miocene silica‐undersaturated alkaline basalts of the Western Qinling orogen, China. These alkaline basalts are associated with carbonatites and are characterized by low SiO2 (39.0–43.2 wt.%) and Al2O3 (6.98–9.15 wt.%) contents, high CaO/Al2O3 ratios (1.4–1.8), and positive Nb–Ta and negative Pb–Zr–Hf–Ti anomalies, suggesting they were derived by partial melting of carbonatite‐metasomatized asthenospheric mantle. The studied samples have δ26Mg values of −0.24‰ to −0.44‰, ranging from mantle‐like values (δ26Mg = −0.25‰ ± 0.07‰) to lower values. This implies that carbonatite metasomatism does not always produce low‐δ26Mg anomalies. The samples have δ44/40Ca values (0.59‰–0.77‰; relative to the standard SRM915a) that are lower than Bulk Silicate Earth (0.94‰ ± 0.05‰), which are attributed to the involvement of low δ44/40Ca recycled carbonate in the mantle source. We suggest that the shift in mantle δ26Mg values during carbonatite metasomatism is controlled by the type and amount of carbonatite involved, while Ca isotope variations depend largely on the δ44/40Ca values of subducted carbonates. Mg or Ca isotopes alone, however, may not be sufficient to track the deep carbon cycle.

High-Precision Measurements of 44Ca/40Ca Using Multiple-Collector Inductively Coupled Plasma Mass Spectrometry without Collision-Cell Technology

“…Comparison between previously reported Ca isotopic data and values measured in this study. Previously reported values are from the literature. ,,− ,,− Gray, red, and blue spots represent data from the literature, this study, and average values of literature values. All the compiled data are listed in Table S9.…”

The Genesis of A‐Type Granites in Lower Yangtze River Belt: Evidence From Calcium Isotopes

“…Major and trace element data of the A-type granites in this article are available in Li et al (2011Li et al ( , 2012. Data collected in literature are in Table S1 in Supporting Information S1 (Antonelli, Yakymchuk, et al, 2023), Table S2 in Supporting Information S1 (Chen & Jahn, 1998;Luo, Wang, et al, 2018;Peng, 2012;Peng et al, 2012;Wu et al, 2012;Yan et al, 2012;Yang, 2015;Zhai et al, 1999;Zhang, 1984;Zhang et al, 1988;Zheng, 1995), Table S3 in Supporting Information S1 (Chen et al, 2019(Chen et al, , 2020(Chen et al, , 2022Kang et al, 2019;Liu et al, 2022;Lu et al, 2020;Qi et al, 2022;Wang et al, 2019Wang et al, , 2021Zhao et al, 2022;Zhu et al, 2018Zhu et al, , 2021, Table S4 in Supporting Information S1 (Antonelli, Yakymchuk, et al, 2023;Fu et al, 2022;Larsen, 1979;Streck & Grunder, 1997;Sun & McDonough, 1989).…”