Magnesium based ternary metal hydrides containing alkali and alkaline-earth elements

Yvon, K.; Bertheville, B.

doi:10.1016/j.jallcom.2006.01.049

Cited by 47 publications

(38 citation statements)

References 37 publications

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“…Zr 2 CoH 5 structure [6] derives from the tetragonal Zr 2 Co structure (I4/mcm space group SG). A change of SG arises from the occupation of H2 atoms of half of the 32 Zr 3 Co tetrahedral holes (i.e. 16 atoms) of the intermetallic in an ordered manner.…”

Section: Relevant Structural Detailsmentioning

confidence: 99%

“…The potential candidates for hydrogen storage in metals belong to two main families: the intermetallic (binary, ternary and quaternary) hydrides and the transition metal hydridocomplexes; also there are the saline metal hydrides based on alkaline and alkaline earth elements [1][2][3]. Several experimental and theoretical reports were devoted to better understand their physical and chemical properties (cf.…”

Section: Introductionmentioning

confidence: 99%

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Drastic changes in electronic, magnetic, mechanical and bonding properties from Zr2CoH5 to Mg2CoH5

Matar¹

2013

Journal of Solid State Chemistry

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Section: Relevant Structural Detailsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Drastic changes in electronic, magnetic, mechanical and bonding properties from Zr2CoH5 to Mg2CoH5

Matar¹

2013

Journal of Solid State Chemistry

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“…Therewith, β-TlPd 3 H which is stable in air under ambient conditions joins the class of ternary hydrides with perovskite structure. Many of them possess a cubic perovskite structure [42][43][44][45][46][47] [20], MgPd 3 D 0.7 [23] and InPd 3 H~0 .8 [31].…”

Section: Page 3 Of 19mentioning

confidence: 99%

Crystal Structure and Formation of TlPd₃and its new Hydride TlPd₃H

Kurtzemann

Kohlmann

2010

Zeitschrift anorg allge chemie

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X-Ray powder diffractionPowder X-Ray diffraction (XRPD) patterns were recorded on a Huber image plate Guinier diffractometer G670 using CuK α1 radiation (λ = 154.053 pm). The measurements were performed using flat transmission samples with the powders fixed on an adhesive tape.Step width of the data was 0.005° in 2θ and silicon was used as internal standard. For Rietveld refinements the programme Full Prof [38] was applied using pseudo-Voigt functions to generate the line shape of the diffraction peaks.

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“…In addition to the Mg containing transition metal complex hydrides, there are a number of complex ternary hydrides comprised of only Mg and an alkali, alkaline or rare earth metal that have been reviewed [70]. Of most interest for thermal storage, from a cost point of view, are Ca4Mg3H14, Ca19Mg8H54 and NaMgH3.…”

Section: Mg-based Complex Hydridesmentioning

confidence: 99%

Metal hydrides for concentrating solar thermal power energy storage

et al. 2016

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The development of alternative methods for thermal energy storage is important for improving the efficiency and decreasing the cost for Concentrating Solarthermal Power (CSP). We focus on the underlying technology that allows metal hydrides to function as Thermal Energy Storage (TES) systems and highlight the current state-of-the-art materials that can operate at temperatures as low as room-temperature and as high as 1100 o C. The potential of metal hydrides for thermal storage is explored while current knowledge gaps about hydride properties, such as hydride thermodynamics, intrinsic kinetics and cyclic stability, are identified. The engineering challenges associated with utilising metal hydrides for high-temperature thermal energy storage are also addressed.

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Magnesium based ternary metal hydrides containing alkali and alkaline-earth elements

Cited by 47 publications

References 37 publications

Drastic changes in electronic, magnetic, mechanical and bonding properties from Zr2CoH5 to Mg2CoH5

Drastic changes in electronic, magnetic, mechanical and bonding properties from Zr2CoH5 to Mg2CoH5

Crystal Structure and Formation of TlPd₃and its new Hydride TlPd₃H

Metal hydrides for concentrating solar thermal power energy storage

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Magnesium based ternary metal hydrides containing alkali and alkaline-earth elements

Cited by 47 publications

References 37 publications

Drastic changes in electronic, magnetic, mechanical and bonding properties from Zr2CoH5 to Mg2CoH5

Drastic changes in electronic, magnetic, mechanical and bonding properties from Zr2CoH5 to Mg2CoH5

Crystal Structure and Formation of TlPd3and its new Hydride TlPd3H

Metal hydrides for concentrating solar thermal power energy storage

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Crystal Structure and Formation of TlPd₃and its new Hydride TlPd₃H