Magnetic and spectroscopic properties of a 2D Mn(II) coordination polymer with carbohydrazone ligand

Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications

“…Antiferromagnets frequently exhibit such spin canting, where the spin carriers are linked by monoatomic bridges . Further, the most frequently encountered magnetic properties in 2D MOFs is the antiferromagnetic ordering, and this is dominated in the Cu­(II) containing 2D MOFs. − ,,− Several Mn­(II) and Co­(II), ,− ,− ,− and a few Fe­(II) and Ni­(II) 2D MOFs with mostly containing (4,4) grid structures have also exhibit this antiferromagnetic ordering. ,− ,− …”

Halide mediated modulation of magnetic interaction and anisotropy in dimeric Co(ii) complexes

“…[4][5][6] These simple organic ligands, along with suitable bridging groups like halides, carboxylates, etc., influence the type and intensity of magnetic interactions between paramagnetic metal ions. [7][8][9][10][11][12][13] Designing acceptable ligand configurations to create novel self-assembled structures is the main challenge for an inorganic synthetic chemist in the synthesis of crystals. 14,15 The overall magnetic properties of the complexes are controlled by the magnetic exchange interaction of the complexes, which determines the SMM behavior of the complexes.…”

Birefringence and polarized luminescence of a manganese(ii) chloride–triphenylphosphine oxide compound: application in LEDs and photolithography

“…It should be noted that Mn(II) complexes have been studied intensively over the past decades [22][23][24][25][26][27][28][29][30] because of their intriguing optical, luminescent, and magnetic properties. [31][32][33][34][35][36][37][38][39][40] Nowadays, luminescent Mn(II) complexes are considered to be promising emitters and phosphors for optics, optoelectronics, and sensors. Such complexes have important advantages such as low cost, solution processability, and unusual photophysical properties.…”