Magnetic Anisotropy of V2O3 Single Crystals

Greenwood, Morris; Mires, Raymond W.; Smith, Alfred R.

doi:10.1063/1.1674989

Cited by 9 publications

(2 citation statements)

References 5 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The chemical and physical properties of the group V oxides-vanadium, niobium, and tantalumshow promise for applications in catalysis, electrochemistry, and electrochromical device technology. V 2 O 3 has been the subject of many investigations due to a remarkable firstorder metal-insulator transition at about 150-160 K, 1,2 from the low-temperature monoclinic 3 into the rhombohedral phase, with an accompanying seven order-of-magnitude increase in conductivity and a shift from antiferromagnetic 4 to paramagnetic [5][6][7][8] behavior. The low-temperature phase also exhibits an increase in volume of about 1.6%.…”

Section: Introductionmentioning

confidence: 99%

Magnetic phase transition inV2O3nanocrystals

et al. 2010

View full text Add to dashboard Cite

Magnetic phase transition in V2O3 nanocrystalsV 2 O 3 nanocrystals can be synthesized through hydrothermal reduction in VO͑OH͒ 2 using hydrazine as a reducing agent. Addition of different ligands to the reaction produces nanoparticles, nanorods, and nanoplatelets of different sizes. Small nanoparticles synthesized in this manner show suppression of the magnetic phase transition to lower temperatures. Using muon spin relaxation spectroscopy and synchrotron x-ray diffraction, we have determined that the volume fraction of the high-temperature phase, characterized by a rhombohedral structure and paramagnetism, gradually declines with decreasing temperature, in contrast to the sharp transition observed in bulk V 2 O 3 .

show abstract

Section: Introductionmentioning

confidence: 99%

Magnetic phase transition inV2O3nanocrystals

et al. 2010

View full text Add to dashboard Cite

show abstract

“…The chemical and physical properties of the Group V oxides − vanadium, niobium, and tantalum − show promise for applications in catalysis, electrochemistry and electrochromical device technology. V 2 O 3 has been the subject of many investigations due to a remarkable first-order metalinsulator transition at about 150-160K, 1,2 from the lowtemperature monoclinic 3 into the rhombohedral phase, with an accompanying seven order-of-magnitude increase in conductivity and a shift from antiferromagnetic 4 to paramagnetic [5][6][7][8] behavior. The low-temperature phase also exhibits an increase in volume of about 1.6%.…”

Section: Introductionmentioning

confidence: 99%

Magnetic phase transition in V2O3 nanocrystals

Blagojevic,

Carlo,

Brus

et al. 2010

Preprint

View full text Add to dashboard Cite

V2O3 nanocrystals can be synthesized through hydrothermal reduction of VO(OH)2 using hydrazine as a reducing agent. Addition of different ligands to the reaction produces nanoparticles, nanorods and nanoplatelets of different sizes. Small nanoparticles synthesized in this manner show suppression of the magnetic phase transition to lower temperatures. Using muon spin relaxation spectroscopy and synchrotron x-ray diffraction, we have determined that the volume fraction of the high-temperature phase, characterized by a rhombohedral structure and paramagnetism, gradually declines with decreasing temperature, in contrast to the sharp transition observed in bulk V2O3.

show abstract

V(0) - V(iii)

König¹,

König²

Magnetic Properties of Coordination and Organometallic Transition Metal Compounds

View full text Add to dashboard Cite

Magnetic Anisotropy of V2O3 Single Crystals

Cited by 9 publications

References 5 publications

Magnetic phase transition inV2O3nanocrystals

Magnetic phase transition inV2O3nanocrystals

Magnetic phase transition in V2O3 nanocrystals

V(0) - V(iii)

Contact Info

Product

Resources

About