Magnetic Behaviour of Submicronic Acicular Composite Particles

Buron, Marie-Pierre; Gougeon, M.; Rousset, Arnaud

doi:10.4028/www.scientific.net/kem.132-136.1420

Cited by 5 publications

(1 citation statement)

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“…In addition, EB has been observed in a variety of ferromagnetic metals and ferrimagnetic oxides. Focusing on oxides, it was reported in double perovskites, manganites, cobaltites, garnets, hexaferrites, and spinel ferrites . For most of these systems, a shift and a broadening of the hysteresis loops were observed in magnetic field cooling operating conditions.…”

Section: Introductionmentioning

confidence: 99%

Giant Exchange‐Bias in Polyol‐Made CoFe₂O₄‐CoO Core–Shell Like Nanoparticles

Flores‐Martínez

Franceschin

Gaudisson

et al. 2018

Part & Part Syst Charact

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Cobalt ferrite ferrimagnetic nanoparticles (NPs) are prepared and used in this work as seeds to grow a thin antiferromagnetic poly‐ and nanocrystalline CoO shell. The major purpose is to study systematically the characteristics of the as‐produced powders, making emphasis on their internal crystallographic arrangement and their magnetic properties. 57Fe Mössbauer spectrometry evidences an evolution of the cation distribution among the spinel lattice in the cobalt ferrite core during the core–shell NPs processing. High‐resolution transmission electron microscopy shows a perfect epitaxy between the face‐centered cubic lattices of the spinel core and the rock‐salt shell. Finally, the measurements of 7T‐field‐cooled magnetic hysteresis loops at low temperature (5 K) of the composite particles exhibit a strong exchange bias coupling with an exchange field, µ0HE, of 365 mT and an enhanced coercive field, µ0HC, of 1395 mT. These values are very high compared to those of differently prepared CoO‐based oxide composite NPs and for which a giant exchange‐bias is reported. These features are attributed to the favorable material processing conditions offered by the polyol process in terms of crystalline quality, particularly at the interfaces, and for the pinning action exerted by the CoO phase on the magnetization of the CoFe2O4 phase.

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Section: Introductionmentioning

confidence: 99%