Magnetic field effects in the infrared multiphoton dissociation of CF2HCl

Duperrex, R.; Bergh, Hubert van den

doi:10.1063/1.439860

Cited by 27 publications

(2 citation statements)

References 7 publications

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“…Fig. 14 Clearly, there is a pronounced increase of yields and rates at a given fluence and intensity, as was found in the experiments on CF,HCI [32,33]. If this mechanism for the enhancement of yields by static fields is dominant, one can make several predictions: (i) At high See also the detailed discussion in the text intensity the effect should be smaller than at low intensity and the same fluence.…”

Section: Km+im K M + I Mmentioning

confidence: 62%

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Master equations for photochemistry with intense infrared light (IV). A unified treatment of case B and case C including nonlinear effects

Qüack

1981

Ber Bunsenges Phys Chem

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A unified master equation for unimolecular reactions induced by monochromatic infrared radiation (URIMIR) is presented. Its effective rate coefficient matrix covers both case B (Pauli equation) and case C, properly including the nonlinearity of the latter. Exact quantum mechanical model solutions are compared with results from the approximate unified master equation. The exact analytical solutions of the master equation are presented for the URIMIR of some realistic molecular models. The important new properties of the transition range between case B and case C are quantitatively discussed with respect to time dependent and steady state level populations, time dependent and steady state rate coefficients and their nonlinear intensity dependence, and with respect to the influence of molecular properties. The role of case C for the interpretation of static field effects and its importance for efficient isotope separation are pointed out.

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Section: Km+im K M + I Mmentioning

confidence: 62%

“…One of the important most recent developments in URIMIR is the discovery by van den Bergh and coworkers [33,32] of the increase in yield when applying static magnetic and electric fields. These effects find a simple explanation within the framework of the transition between case C and case B.…”

Section: The Effect Of External Fields and Collisionsmentioning

confidence: 99%