Faraday
rotation spectroscopy (FRS) exploits the magneto-optical
effect to achieve highly selective and sensitive detection of paramagnetic
molecules. Usually, a solenoid coil is used to provide a longitudinal
magnetic field to produce the magneto-optical effect. However, such
a method has the disadvantages of excessive power consumption and
susceptibility to electromagnetic interference. In the present work,
a novel FRS approach based on a combination of a neodymium iron boron
permanent magnet ring array and a Herriott multipass absorption cell
is proposed. A longitudinal magnetic field was generated by using
14 identical neodymium iron boron permanent magnet rings combined
in a non-equidistant form according to their magnetic field’s
spatial distribution characteristics. The average magnetic field strength
within a length of 380 mm was 346 gauss. A quantum cascade laser was
used to target the optimum 441 ← 440 Q-branch
nitrogen dioxide transition at 1613.25 cm–1 (6.2
μm) with an optical power of 40 mW. Coupling to a Herriott multipass
absorption cell, a minimum detection limit of 0.4 ppb was achieved
with an integration time of 70 s. The low-power FRS nitrogen dioxide
sensor proposed in this work is expected to be developed into a robust
field-deployable environment monitoring system.