Magnetic instability and f – d hybridization in CeFe 2 on substituting Cr, Ag, and Au for Fe

Abstract

Hybridization between Ce f and conduction d states has been speculatively known to be one of the mechanisms responsible for magnetic instability of the ferromagnetic ground state of CeFe2. Substituting Fe by small amounts of certain elements stabilizes it to an antiferromagnetic state below the Curie temperature via a first-order second phase transition. In the present work, we seek any direct relation between the f −d hybridization and the second transition by measuring primarily dc magnetization and Ce M4,5 edge x-ray absorption spectra of Ce(Fe1−xMx)2 pseudobinaries, with M = Cr, Ag and Au. X-ray diffraction and x-ray photoelectron spectroscopy measurements are also performed essentially to monitor the quality of the samples. Whereas Cr impurity is found to cause the second transition, Ag and Au apparently do not induce any. In the former, the Curie and second transition temperatures vary systematically, but differently, with x. Our results imply that there is a definite proportionality between the x dependences of the second transition temperature and the f − d hybridization strength estimated qualitatively from the absorption spectra.

Bimetallic AgFe Systems on Mordenite: Effect of Cation Deposition Order in the NO Reduction with C3H6/CO

“…Some studies [22,23] have shown that zeolite-based multi-metallic materials exhibit a synergistic effect in comparison with monometallic materials. The interaction of Ag and Fe supported on different zeolite carriers has been the subject of many modern studies because it affects the catalytic [24], ferromagnetic [25], electronic [26], luminescence [27], and other properties. Being relatively inexpensive materials [28], Ag-based bimetallic materials with transition metal additives have acquired a great interest, showing excellent catalytic activities for reduction of NO x [29,30].…”