Magnetic interactions in the layer compounds MPX3 (M = Mn, Fe, Ni; X = S, Se)

Flem, G. Le; Brec, R.; Ouvard, G.; Louisy, A.; Ségransan, P.

doi:10.1016/0022-3697(82)90156-1

Cited by 233 publications

(169 citation statements)

References 11 publications

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“…The thermal variation of the magnetic anisotropy stabilizes three possible spin arrangements that are nearly degenerated: (i) a plain antiferromagnetic (AF) state between 48 …”

Section: Magnetic Propertiesmentioning

confidence: 99%

Layered Organic–Inorganic Materials: A Way towards Controllable Magnetism

2003

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The search for new materials for tailor‐made applications and new devices involves not only solid‐state chemists, physicists or materials engineers, but also the area molecular and organo‐metallic chemistry, and even biochemistry. This is especially clear in the field of organic–inorganic multifunctional materials, whose design necessitates to investigate new concepts and principles developed in these different disciplines. Here, the authors review the structure‐magnetic property relationships in layered structures, made of organic and inorganic subunits.

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“…The thermal variation of the magnetic anisotropy stabilizes three possible spin arrangements that are nearly degenerated: (i) a plain antiferromagnetic (AF) state between 48 …”

Section: Magnetic Propertiesmentioning

confidence: 99%

Layered Organic–Inorganic Materials: A Way towards Controllable Magnetism

2003

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“…The magnetic structure of MnPS 3 consists of Mn ions coupled antiferromagnetically to their three nearest neighbors in the layer [4,5]. On the other hand, in FePS 3 , Fe spins are ferromagnetically coupled with two of the three nearest neighbors and antiferromagnetically with third one and form zigzag spin chains coupled antiferromagnetically in the layer [4,6]. In both compounds, the inter-layer coupling of spins is antiferromagnetic and the direction of the magnetic moment in the ordered state is perpendicular to the c plane.…”

Section: Introductionmentioning

confidence: 99%

Phase diagram, magnetic properties and specific heat of Mn1−xFexPS3

Masubuchi

Hoya

Watanabe

et al. 2008

Journal of Alloys and Compounds

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“…were identified as van der Waals layered antiferromagnets [23], and they have been revisited recently in light of their potential for studying monolayer materials [24][25][26]. Although antiferromagnetic materials are in some ways less "functional" than ferromagnetic materials, interest in them is growing as ideas for their use as robust spintronic materials develop [27][28][29].…”

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confidence: 99%

Antiferromagnetism in the van der Waals layered spin-lozenge semiconductor CrTe3

McGuire

Garlea

et al. 2017

Phys. Rev. B

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The crystallographic, magnetic, and transport properties of the van der Waals bonded, layered compound CrTe3 have been investigated on single crystal and polycrystalline materials. The crystal structure contains layers made up of lozenge shaped Cr4 tetramers. Electrical resistivity measurements show the crystals to be semiconducting, with a temperature dependence consistent with a band gap of 0.3 eV. The magnetic susceptibility exhibits a broad maximum near 300 K characteristic of low dimensional magnetic systems. Weak anomalies are observed in the susceptibility and heat capacity near 55 K, and single crystal neutron diffraction reveals the onset of long range antiferromagnetic order at this temperature. Strongly dispersive spin-waves are observed in the ordered state. Significant magneto-elastic coupling is indicated by the anomalous temperature dependence of the lattice parameters and is evident in structural optimization in van der Waals density functional theory calculations for different magnetic configurations. The cleavability of the compound is apparent from its handling and is confirmed by first principles calculations, which predict a cleavage energy 0.5 J/m 2 , similar to graphite. Based on these results, CrTe3 is identified as a promising compound for studies of low dimensional magnetism in bulk crystals as well as magnetic order in monolayer materials and van der Waals heterostructures.

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Magnetic interactions in the layer compounds MPX3 (M = Mn, Fe, Ni; X = S, Se)

Cited by 233 publications

References 11 publications

Layered Organic–Inorganic Materials: A Way towards Controllable Magnetism

Layered Organic–Inorganic Materials: A Way towards Controllable Magnetism

Phase diagram, magnetic properties and specific heat of Mn1−xFexPS3

Antiferromagnetism in the van der Waals layered spin-lozenge semiconductor CrTe3

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