Magnetic nanoporous coordination polymers

1D Chain Crystal Structure of Copper(II) Oxalate Containing a 4,4'-Bipyridine and 1,10-Phenanthroline Ligands: [Cu2(ox)(4,4'-bpy)(phen)2](NO3)2

“…[4][5][6] The most commonly used strategy for designing such materials relies on the utilization of multidentate N-or O-donor ligands which have the capacity to bridge between metal centers to form polymeric structures. For example, 4,4'-bipyridine (4,4'-bpy) is an excellent ligand and a number of one-, twoand three-dimensional infinite metal-4,4'-bpy frameworks have been generated.…”

Synthesis, Crystal Structures and Properties of New Barium Thiocyanato Coordination Polymers with trans-1,2-Bis(4-pyridyl)ethylene as Ligand

“…3, bottom). 4 (2) Compound 2 crystallizes in the triclinic space group P1 with Z = 1 formula unit in the unit cell (see Table 7). The asymmetric unit contains one Ba cation, two thiocyanato anions, three bpe ligands, and three water molecules in general positions and one bpe ligand located on a center of inversion.…”

“…Recently, investigations on the synthesis, structures and properties of coordination compounds have become of increasing interest [1][2][3][4][5][6][7]. In this context, compounds with condensed networks, in which paramagnetic metal atoms are linked by small-sized anionic ligands are of special interest because of their diverse magnetic properties.…”

Synthesis, Structures and Properties of Cobalt Thiocyanate Coordination Compounds with 4-(hydroxymethyl)pyridine as Co-ligand

“…For this purpose, structure-property relationships are investigated systematically and strategies for a rational construction of their crystal structures are required. Compounds that consist of paramagnetic metal cations are of particular interest because they can show different magnetic properties and thus it is not surprising that an increasing number of new compounds were recently reported [5][6][7][8][9][10][11][12][13][14]. One group of these compounds are transition metal thiocyanato coordination polymers, which show a variety of different coordination modes including the terminal and the bridging coordination, with the latter being of special importance because cooperative magnetic properties can be expected [15][16][17][18][19][20][21][22][23][24][25][26][27][28][29][30][31][32][33][34].…”