Magnetic probing of transition states

Buchachenko, A. L.; Tarasov, V. F.; Ghatlia, Naresh D.; Turro, Nicholas J.

doi:10.1016/0009-2614(92)85443-e

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1993

1995

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Cited by 2 publications

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“…27 The relationship between Pr and Pd is shown in Figure 5 which emphasizes that the ratio PJP& = 6.6 ± 0.6 does not depend on the magnetic field up to 15 kG, strongly supporting an idea that the reaction trajectories for the head-to-head RP reaction, R and L recombinations and disproportionation, are magnetically equivalent. 19 Similar but more complicated equations for the decay of optical activity have been derived for the Pr and disproportionation Pd probabilities; Pr/Pd = 6.6 ± 0.2 and does not depend on the magnetic field in contrast to the individual Pr and Pd values (cf. Figure 4).…”

Section: Phc-chphmentioning

confidence: 76%

“…This is a very important and general principle of magnetic equivalence of the reaction trajectories in RPs which has been formulated recently. 19 The purpose of all the equations derived above is to describe the chemically induced isotope fractionation between the reaction products as a function of chemical conversion according to the following logic:…”

Section: Reactionsmentioning

confidence: 99%

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