Sputtering-made magnetic thin films with metal-ceramic multilayer structures have been reported to achieve excellent magnetic properties and/or new functions for various magnetic materials. However, sputtering-made magnetic films tend to have 10 or fewer layers because main applications of thin films, such as magnetic sensors, recording heads and recording media, require thin films thinner than 1 μm. This paper reports an Fe-Co/ glass multilayer thick-film that has approximate thickness of 10 μm (above 100 layers). This thick-film was prepared via pulsed laser deposition using several composite targets (two- or three-layer target) consisting of an Fe-Co alloy (or Fe-Co sheet) and a glass plate. The fabrication of an Fe-Co single-layer film and a glass single-layer film was examined to determine the optimal defocus rate for the composite target. Then, we confirmed that the use of a [glass plate]/[Fe-Co alloy] two-layer target enabled the local formation of a [20 nm-thick Fe-Co]/[10 nm-thick glass) laminated structure with approximately 130 layers. An Fe-Co/glass multilayer structure was formed by using a three-layer target of a [Fe-Co sheet]/[glass plate]/[metal alloy]. Nonetheless, the results also suggest that large glass droplets should be removed in future work to create homogeneous multilayer thick-films.