Magnetic properties and Moessbauer spectra of several iron(III)-dicarboxylic acid complexes

Dziobkowski, C.; Wrobleski, James T.; Brown, David B.

doi:10.1021/ic50217a007

Cited by 103 publications

(54 citation statements)

References 3 publications

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“…Synthesis: The trimeric iron(iii) acetate SBU was first prepared according to Dziobkowski et al [33] Subsequently, iron(iii) acetate, fumaric acid (HO 2 C-C 2 H 2 -CO 2 H; Acros, 99 %) or trans,transmuconic acid (HO 2 C-C 4 H 4 -CO 2 H; Aldrich, 98 %), sodium hydroxide (Aldrich, 97 %), deionized water, and methanol (Prolabo, 99 %) were mixed in the following ratios: 1:3:1.5:50:1000 (based on one trimer). The resulting orange gels were aged at 100 8C for 3 days in a teflonlined Parr bomb and cooled down to room temperature.…”

Section: Methodsmentioning

confidence: 99%

A Route to the Synthesis of Trivalent Transition‐Metal Porous Carboxylates with Trimeric Secondary Building Units

et al. 2004

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Section: Methodsmentioning

confidence: 99%

A Route to the Synthesis of Trivalent Transition‐Metal Porous Carboxylates with Trimeric Secondary Building Units

et al. 2004

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“…26,27 Herein, we report the synthesis of the Mnbased analogue of the MIL-100 structure that could be obtained using Mn(II)nitrate as the metal source. The divalent ions are 5 oxidized in-situ in methanolic solution. The Mn-MIL-100 was fully characterised by TG-measurements, X-ray powder diffraction (XRPD), IR-spectroscopy and sorption experiments.…”

Section: +mentioning

confidence: 99%

“…Thus, two dominating mechanisms are taking place during the crystallisation of Mn-MIL-100, which was already reported in other studies. 33 Therefore, the Sharp-Hancock analysis was 5 carried out for both linear sections. The final values are summarized in Tab.…”

Section: Reaction Mechanismmentioning

confidence: 99%

“…1. 5 This cluster has been known for a very long time, but the chemistry of MOFs shed a new light on its properties. Especially the compounds known as MIL-88 3 (MIL stands for Materiaux de 30 l'Institute Lavoisier), MIL-100 6 and MIL-101 7 , which are all based on this building unit, must be mentioned in this context.…”

Section: Introductionmentioning

confidence: 99%

“…The lattice parameters are very similar (73.299(3) Å and 72.906 Å for Mn-and Cr-MIL-100 respectively, see supporting informations Fig, S17) and the differences in relative intensities are mainly due to the occluded solvent molecules. Depending on the amount and kind of solvent occluded inside the pores, the 5 relative intensity of the reflections may strongly vary. The framework structure is stable in methanol as well as in ethanol.…”

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Formation and characterisation of Mn-MIL-100

2013

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The synthesis and characterisation of the Mn-based analogue of the MIL-100-framework is reported. The 5 title compound is synthesised from a methanolic solution of trimesic acid and manganese(II) nitrate in very short reaction times. During the reaction, the Mn 2+ -ions are oxidized in-situ to Mn 3+ -ions. The obtained MOF was characterised by XRPD-measurements, IR-spectroscopy, thermogravimetric measurements and sorption experiments. To have a closer look at the crystallisation occurring after the in situ metal oxidation-reaction that results in the formation of the title compound, in-situ EDXRPD-10 experiments under solvothermal conditions were carried out. These time-resolved measurements could be evaluated by two different kinetic models (by Avrami and Gualtieri) for crystallisation. The results indicate a two stage reaction process, which are dominated by different reaction mechanisms.

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Oberflächenkoordinationschemie: Korrosionsschutz durch Bildung vierkerniger Eisenkomplexe mit Salicylaldoximen als Liganden

et al. 1999

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Ein vierkerniger Eisencluster ist die Hauptkomponente der violetten Schutzschichten, die bei der Behandlung von Flußstahl‐Oberflächen mit Salicylaldoximen als Korrosionshemmern entstehen. Dies ergab der Vergleich ihrer spektroskopischen Daten mit denen des Clusters [{Fe(salH)(HsalH)}4], der aus FeCl3 und Salicylaldoxim (H2salH) erhalten wurde und eine verzerrt tetraedrische Anordnung von FeIII‐Ionen enthält, die von terminalen (1−) und verbrückenden (2−) Salicylaldoximat‐Liganden koordiniert sind (der Clusterkern ist gezeigt).

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Magnetic properties and Moessbauer spectra of several iron(III)-dicarboxylic acid complexes

Cited by 103 publications

References 3 publications

A Route to the Synthesis of Trivalent Transition‐Metal Porous Carboxylates with Trimeric Secondary Building Units

A Route to the Synthesis of Trivalent Transition‐Metal Porous Carboxylates with Trimeric Secondary Building Units

Formation and characterisation of Mn-MIL-100

Oberflächenkoordinationschemie: Korrosionsschutz durch Bildung vierkerniger Eisenkomplexe mit Salicylaldoximen als Liganden

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