-directional correlations have been measured between the ground state band transitions 6~4, 4-,2 and 2~0 and the 7-rays depopulating the levels of the gamma vibrational band and the negative parity states of 166Er. Thereby angular momenta could be assigned to the latter states and M2/E1 multipole mixtures determined for the depopulating 7-transitions. The E2/M1 mixing ratios were obtained for a series of I~Ig transitions up to I~=8 +. These are used to investigate the angular momentum dependence of the E2/M 1 admixtures.