Magnetic Properties of LnMnO3 (Ln=Ho, Er, Tm, Yb, and Lu)

Crystal structure, magnetic and dielectric behavior of h-LuMn O3± ceramics (0.95≤x≤1.04)

“…Furthermore, by increasing the ratio x large differences of the magnetic susceptibility measured in ZFC and FC conditions appeared below T N . Such irreversibility or spin-glass like behaviour in ZFC/FC magnetic measurements was also observed in h-RMnO 3 [10,22,[30][31][32][33]. The reciprocal of magnetic susceptibility,  -1 , deviates from the linear dependency on temperature expected from Curie-Weiss law in the paramagnetic region approaching T N .…”

Breaking the geometric magnetic frustration in controlled off-stoichiometric LuMn1+zO3+δ compounds

“…In addition, TG experiments revealed an enhanced mass exchange at ~500 K, which is thermodynamically 300º lower than typically found in perovskite systems. 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 for the series of samples LuM-"094"; "098"; "099"; "100"; "101" respectively and from referenced data [5,[11][12][13][14][15][16][17][18][19][20][21]. b) Example of XRD and Rietveld refinement of sample LuM098.…”

Magnetic and magnetotransport properties of the orthorhombic perovskites(Lu,Ca)MnO3

“…The values obtained for the x = 0.0, 0.5, and 1.0 samples are in good agreement with those previously reported for the same compositions. 12,14,20 With increasing x, the lattice parameters change in a continuous manner indicating perfect solid solubility of Ca at the Lu site: Parameters a and c increase slightly, whereas b decreases strongly. As a consequence, the unit-cell volume also decreases.…”

“…14 This is in accordance with the results of previous work on ͑Lu 0.5 Ca 0.5 ͒MnO 3 . 12,14 Compositions 0.8Յ x Յ 0.95. For the heavily Casubstituted ͑Lu 1−x Ca x ͒MnO 3 samples of 0.8Յ x Յ 0.95, an FM component was clearly observed in the -T data ͑Fig.…”

“…[10][11][12][13] At the same time, efforts to dope the metastable phases with carriers have been rarely reported and so far focused on limited A-for-R substitution levels. 12,[14][15][16][17][18] In the present contribution, magnetic and magnetotransport properties are reported for the ͑Lu 1−x Ca x ͒MnO 3 system over the whole Ca-for-Lu substitution range, 0.0Յ x Յ 1.0.…”