Magnetic Properties of Mn-Doped Amorphous SiO₂Matrix

Abstract

Samples of Mn-doped amorphous SiO 2 matrix with manganese concentration 0.7 and 3 at.% have been prepared by a sol-gel method. Transmission electron microscopy analysis has shown that the samples contain agglomerates of amorphous silica particles 10 -20 nm in size. Two types of Mn-rich particles are dispersed in silica matrix, smaller nanoparticles with dimensions between 3 and 10 nm, and larger crystalline areas consisting of aggregates of the smaller nanoparticles. High-temperature magnetic susceptibility reveals that dominant magnetic phase at higher temperatures is λ-MnO 2 . At temperatures below T C = 43 K strong ferrimagnetism originating from the minor Mn 3 O 4 phase masks the relatively weak magnetism of λ-MnO 2 . Magnetic field dependence of the maximum in the zero-field-cooled magnetization for both the samples in the vicinity of 40 K, and a frequency shift of the real component of the AC magnetic susceptibility in the sample with 3 at.% Mn suggest that the magnetic moments of the smaller Mn 3 O 4 nanoparticles with dimensions below 10 nm are subject to thermally activated blocking process just below the Curie temperature T C . The low-temperature maximum in the zero-field-cooled magnetization observed for both the samples below 10 K indicates possible spin glass freezing of the magnetic moments in the geometrically frustrated Mn sublattice of the λ-MnO 2 crystal structure.

Nanographene Magnetic Properties: A Monte Carlo Study

“…For h = 3.5 kOe and low temperatures, T < 2 K. This behavior was observed in Ref. [20]. All these curves show divergence between the FC and ZFC data.…”