Magnetic properties of R – T hydrides (Ho, Y) 6 Fe 23 H 15

Influence of aluminum substitution on the magnetic couplings in R-T alloys Ho6Fe23−xAlx

“…Intermetallic alloys between rare-earth ͑R͒ and 3d-transition ͑T͒ elements with a magnetic compensation temperature, such as R 6 Fe 23 , are important for high-density magneto-optical recording, for hydrogen storage, 1 and for basic studies. 2 All R 6 Fe 23 compounds crystallize in the cubic ͑Fm3m͒ Th 6 Mn 23 structure, R being located in site ͑24e͒ and Fe occupying the four distinct positions ͑4b, 24d, 32f 1 , and 32f 2 ͒.…”

Neutron diffraction study of Ho5YFe23 and Ho5YFe23D16 deuteride

“…It is to be noted that the yttrium-substitution rate x = 1 corresponds to the most canted magnetic structures observed in the magnetization experiments [3].…”

“…We tried to quantify the canting observed previously in hydride of Ho 6−x YFe 23 alloys [3,4] by first adding a z component for the Ho moment in the Fullprof refinement. Only a small z component could be obtained for an equivalent quality of fit (Table 2).…”

“…We presented recently low magnetic field results of yttrium-substituted Ho 6 Fe 23 intermetallic alloys and their corresponding hydrides Ho 6−x Y x Fe 23 H z (x = 0.5, 1; z = 16) [3,4]. The "non-magnetic" yttrium-substitutes Ho on the unique rare-earth site for both compounds.…”

High magnetic field properties of yttrium-substituted Ho6Fe23 alloys and deuterides

“…Intermetallic alloys between heavy rare-earth ͑R͒ and 3d-transition elements ͑T͒, such as R 6 Fe 23 , are important for high density magneto-optical recording, hydrogen storage, 1 and for the basic studies. 2 Furthermore as some of them present a magnetic compensation temperature ͑T comp ͒, they are also potential candidates for high density magnetooptical recording.…”