1985
DOI: 10.1063/1.335089
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Magnetic susceptibility and magnetic resonance in the ordered state of single-crystal [NH3(CH2)2HN3]CuBr4

Abstract: Singlecrystal ac susceptibility measurements on [Co(NH3)6][CuCl5], a 3D, S=1/2 Heisenberg antiferromagnet

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Cited by 28 publications
(8 citation statements)
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“…3,12,18,28 The strength of these interaction, which are invariable antiferromagnetic, decreases rapidly with the BrBr distance. 14 The room temperature magnetic moment of the (dmamtH) 2 -CoBr 4 complex is 4.69 BM and is typical for noninteracting or weak interacting high spin d 7 cobalt ions. The effective magnetic moments were calculated by µ eff = 2.828(χ M × T) 1/2 .…”
Section: Resultsmentioning
confidence: 99%
“…3,12,18,28 The strength of these interaction, which are invariable antiferromagnetic, decreases rapidly with the BrBr distance. 14 The room temperature magnetic moment of the (dmamtH) 2 -CoBr 4 complex is 4.69 BM and is typical for noninteracting or weak interacting high spin d 7 cobalt ions. The effective magnetic moments were calculated by µ eff = 2.828(χ M × T) 1/2 .…”
Section: Resultsmentioning
confidence: 99%
“…27 In [CuBr 4 22 ] species, the J value is usually weaker than 240 K, with few examples of stronger exchange interactions known. For example, the strongest reported interaction is in catena-ethylenediammonium tetrabromocuprate with J = 2136.8 K, 40,41 this exchange is associated with an extremely short inter-bromide distance, 3.6 Å, and a Cu-Br … Br angle = 157.7u. The number of known examples of two-halide exchange of coordination sphere CuL 2 X 2 is smaller.…”
Section: Discussionmentioning
confidence: 99%
“…However, the most common structure is the perovskite-like structure [1]. A wide variety of different organic and inorganic starting compounds are successfully incorporated in this type of organic-inorganic hybrids perovskites and have been used in many research and practical fields such as thermal energy storage (the advantage of remaining solid after the phase change) [2][3][4][5][6]. Now that certified energy conversion efficiencies for solar cells based on mixed organicinorganic are above 20% [7][8][9].…”
Section: Issn(e): 2223-1331/issn(p): 2226-5724mentioning
confidence: 99%