“…27 In [CuBr 4 22 ] species, the J value is usually weaker than 240 K, with few examples of stronger exchange interactions known. For example, the strongest reported interaction is in catena-ethylenediammonium tetrabromocuprate with J = 2136.8 K, 40,41 this exchange is associated with an extremely short inter-bromide distance, 3.6 Å, and a Cu-Br … Br angle = 157.7u. The number of known examples of two-halide exchange of coordination sphere CuL 2 X 2 is smaller.…”