Magnetism in U2T2X compounds

Abstract

Magnetism in UT2X2 compoundsHavela, L.; Sechovsky, V.; Svoboda, P.; Nakotte, H.; Prokes, K.; de Boer, F.R.; Seret, A.; Winand, J.M.; Rebizant, J.; Spirlet, J.C.; Purwanto, A.; Robinson, R.A. General rightsIt is not permitted to download or to forward/distribute the text or part of it without the consent of the author(s) and/or copyright holder(s), other than for strictly personal, individual use, unless the work is under an open content license (like Creative Commons). Disclaimer/Complaints regulationsIf you believe that digital publication of certain material infringes any of your rights or (privacy) interests, please let the Library know, stating your reasons. In case of a legitimate complaint, the Library will make the material inaccessible and/or remove it from the website. Please Ask the Library: http://uba.uva.nl/en/contact, or a letter to: Library of the University of Amsterdam, Secretariat, Singel 425, 1012 WP Amsterdam, The Netherlands. You will be contacted as soon as possible. Download date: 10 May 2018Journal of Magnetism and Magnetic Materials 140-144 (1995) AbstractMagnetic and other electronic properties are presented for the U2T2X compounds (T = late transition metal, X = Sn or In), that crystallize in the tetragonal U3Si2-type structure. They show the formation of 5f magnetic moments and antiferromagnetic ordering in compounds where weak 5f-d hybridization is expected. Near the onset of magnetic ordering strongly enhanced y-values are found. Neutron-diffraction experiments on U2Pd2Sn and U2Pd2In point to a connection between the mutual coordination of U atoms and the type of magnetic anisotropy.

Synthesis, Crystal Chemistry, and Physical Properties of Ternary Intermetallic CompoundsAn2T2X(An=Pu, Am;X=ln, Sn;T=Co, Ir, Ni, Pd, Pt, Rh)

“…The fitted * values in these compounds are quite similar to those previously found in analogue compounds with U (9). In all compounds the values are negative, indicating the existence of antiferromagnetic interactions, although the values are consistently smaller in these Pu analogues than in the U analogues (9). C constants, as defined by Amoretti and Fournier (19) are used instead (see Table 4).…”

Antiferromagnetic ordering in the heavy-fermion systemCe2Au2Cd

“…3 Among other isostructural indides, the highest γ = 500 mJ/mol K 2 is observed for non-magnetic heavy fermion system Ce 2 Pt 2 In. 4 To the best of our knowledge, 22,23 In the context of cerium intermetallics Ce 2 Au 2 Cd can be discussed in line with the equiatomic compounds CePdIn (700 mJ/mol K 2 ) and CePtIn (> 500 mJ/mol K 2 ). [24][25][26] In Fig.…”

Structure and magnetism of R2T2X compounds and their hydrides; comparison of lanthanides and actinides

“…This situation deserves a more detailed analysis. The shortest U-U spacing is in most cases equivalent to the lattice parameter c. Table 1 reveals that the weak paramagnet U 2 Co 2 In [13] has indeed a smaller shortest U-U spacing than the heavy fermion compound U 2 Co 2 Sn, with non-Fermi liquid features [13,14] appearing at the verge of magnetic order.…”