Magneto‐optical, thermal, and mechanical properties of polycrystalline Tb₃Al₅O₁₂ transparent ceramics

Abstract

Terbium aluminum garnet (Tb3Al5O12, TAG) ceramics have become a promising magneto‐optical material owing to the outstanding comprehensive performance, including the magneto‐optical, thermal, and mechanical properties. Fine‐grained TAG ceramics with high optical quality and mechanical properties have attracted much attention. In this study, TAG ceramics with fine grains and high optical quality are fabricated successfully by a two‐step sintering method from co‐precipitated nano‐powders. After pre‐sintered at 1525°C in vacuum and hot isostatic pressed at 1600°C, the in‐line transmittance of TAG ceramics reaches 81.8% at 1064 nm, and the average grain size is 7.1 μm. The Verdet constant of TAG ceramics is −179.6 ± 4.8 rad T−1 m−1 at 633 nm and −52.1 ± 1.9 rad T−1 m−1 at 1064 nm, higher than that of commercial Tb3Ga5O12 crystals. The thermal conductivity of TAG ceramics is determined from 25 to 450°C, and the result is 5.12 W m−1 K−1 at 25°C and 3.61 W m−1 K−1 at 450°C. A comparison of mechanical properties between large‐ and fine‐grained TAG ceramics fabricated under different conditions is conducted. The fine‐grained TAG ceramics possess a bending strength of 226.3 ± 16.4 MPa, which is 9.7% higher than that of the large‐grained ceramics. These results indicate that reducing the grain size on the premise of high optical quality helps improve the comprehensive performance of TAG ceramics.

Effect of Y substitution on the microstructure, magneto-optical, and thermal properties of (Tb 1− x Y x ) 3Al 5O 12 transparent ceramics

“…Based on the estimated values of refractive indices, the theoretical transmittances can be calculated by Eq. ( 1) [61]:…”

Highly transparent Tb3Al5O12 ceramics for kilowatt‐level Faraday isolator

“…Though many studies have been carried out, [10][11][12][13] further improvement on the optical quality and size of TAG single crystals is still needed. In these years, the preparation technology of transparent ceramics developed rapidly, [14][15][16][17][18][19] and extensive investigations [20][21][22][23][24][25] were carried out on transparent TAG ceramic fabrication without melting the material. Compared with its single crystal counterpart, TAG ceramics can be prepared with high quality more easily because they avoid the issue of incongruent melting.…”