We have investigated the influence of chromium (Cr) doping on the magneto-electrical properties of polycrystalline samples La0.75Sr0.25Mn1-xCrxO3 (0.15 ≤ x ≤ 0.25), prepared by the sol-gel method. Comparison of experimental data with the theoretical models shows that in the metal-ferromagnetic region, the electrical behavior of the three samples is quite well described by a theory based on electron-electron, electron-phonon and electron-magnon scattering and Kondo-like spin dependent scattering. For the high temperature paramagnetic insulating regime, the adiabatic small polaron hopping (SPH) model is found to fit well the experimental curves.