We have investigated structural, magnetic, and magnetocaloric properties of monovalent Ag-doped La 1−x Ag x MnO 3 (0.05 ≤ x ≤ 0.25) compounds. The materials were prepared by the sol-gel method and then characterized by X-ray diffraction (XRD). The XRD results indicated that all the samples have a single phase of hexagonal (rhombohedral) structure with the R3c space group. The morphology and particle size distributions were investigated using scanning electron microscopy (SEM) with energy-dispersive spectroscopy (EDS). The SEM images showed that the grain sizes are smaller than 1 μm and remain the same with increasing Ag concentrations. The magnetic properties were studied by measuring magnetization and varying temperature (M(T )) and external magnetic field (M(H )). The M(T ) measurements show that with decreasing temperature all samples exhibit a paramagnetic-to-ferromagnetic phase transition. The Curie temperature, T C , increases from 200 to 290 K as Ag doping increases from 0.05 to 0.25. The magnetic entropy change (|−SM|) is obtained in all samples near the Curie temperatures at a magnetic field change of 3 T. Furthermore, their maximum relative cooling power (RCP) values were found A. Coşkun to be 82.492, 82.614, and 127.375 J/kg for x = 0.10, 0.15, and 0.25.