We measured magnetotransport properties of PbS single crystals which exhibit the quantum linear magnetoresistance (MR) as well as the static skin effect that creates a surface layer of additional conductivity. The Shubnikov-de Haas oscillations in the longitudinal MR signify the peculiar role of spin-orbit coupling. In the angular-dependent MR, sharp peaks are observed when the magnetic field is slightly inclined from the longitudinal configuration, which is totally unexpected for a system with nearly spherical Fermi surface and points to an intricate interplay between the spin-orbit coupling and the conducting surface layer in the quantum transport regime. PACS numbers: 72.20.My, 71.18.+y, 73.25.+i, Recently, non-trivial consequences of the spin-orbit coupling (SOC) in crystalline solids are a major theme in condensed matter physics [1]. For example, the spin Hall effect is a striking manifestation of the SOC in non-magnetic materials [2], and the SOC in noncentrosymmetric superconductors gives rise to an unconventional order-parameter symmetry [3]. Even more strikingly, it was recognized that a certain class of narrow-gap semiconductors where the energy gap is a product of the SOC are topological insulators, whose valence band structures is characterized by a non-trivial Z 2 topological invariant [4][5][6][7][8][9]. The three-dimensional topological insulators host helically spin-polarized surface states and are predicted to exhibit various novel phenomena [7][8][9][10][11]. After the discovery of the topologicalinsulator nature in Bi 1−x Sb x , Bi 2 Se 3 , and Bi 2 Te 3 [12-15], those three materials are under intense investigations.In this context, the narrow-gap semiconductor PbS would make a useful comparison, because its energy gap is due to a strong SOC but its valence band structure lends itself to the trivial Z 2 topological class [8]; namely, PbS is a non-topological insulator. Nevertheless, this material may be called an "incipient" spin Hall insulator, since the energy gap of the SOC origin in PbS causes a large Berry phase in the Bloch states and leads to a finite intrinsic spin Hall conductivity σ s H even in the insulating state [16]. Therefore, the role of the SOC in the transport properties of this material is worth investigating with the modern understanding.PbS has a rock salt crystal structure and has a direct energy gap of about 0.3 eV located at the four equivalent L points of the Brillouin zone [17]. Depending on whether S is excessive or deficient, both p-and n-type PbS can be prepared, and in both cases the Fermi surface (FS) is very nearly spherical [17,18]. This material was well studied in the past for its potential in the infrared applications [17]. More recently, PbS is attracting attentions in the photovoltaic community because of the multi-exiton generation [19]. In this Letter, we report our detailed study of the magnetoresistance (MR) sample, which exhibits a deviation from the classical linear behavior (shown by the solid straight line) and a saturation above 4 T in the quantu...