Manganese

Crisp, Russell I.; Seddon, Kenneth R.

doi:10.1016/s0010-8545(00)80482-8

Cited by 6 publications

(2 citation statements)

References 190 publications

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“…The dimer has Q symmetry with each metal atom in a tetragonally distorted environment. The [Mn(EtOH) 4 ] +2 cation is linked to two trans oxygen atoms of salicylate groups in the anion to give six-coordination about the Μη(Π) centres. The cations thus link the anions in an infinite network.…”

Section: μη(π)-μη(πι) Compoundsmentioning

confidence: 99%

Manganese Coordination Compounds: Classification and Analysis of Crystallographic and Structural Data

Holloway¹,

Melnı́k²

1996

Reviews in Inorganic Chemistry

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This review summarises over seven hundred ciystallographic structures of manganese coordination compounds. In most the manganese is six coordinated, but there are examples from two to eight coordinated. The nuclearity ranges from monomelic to polymeric, and a wide range of ligand systems are found, which parallels the rich chemistry of manganese. The structures are discussed in terms of the coordination about the metal atoms, and correlations are drawn between donor atom, bond length and inteibond angles. There are several examples of distortion isomerism and CONTENTS 0. Abbreviations

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Section: μη(π)-μη(πι) Compoundsmentioning

confidence: 99%

Manganese Coordination Compounds: Classification and Analysis of Crystallographic and Structural Data

Holloway¹,

Melnı́k²

1996

Reviews in Inorganic Chemistry

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“…[1][2][3][4] To date, much effort has been made in the rational design and preparation of FCCs. [5][6][7] Among them, manganese-containing FCCs are especially attractive not only because of their abundant magnetochemical and biochemical behaviours, [8][9][10] but also because of their low cost and nontoxicity that allow them can be used as homogeneous catalysts. [11][12][13][14] Recently, some manganese-containing FCCs have been designed and prepared.…”

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confidence: 99%

A Novel Manganese Complex with Mixed Ligands: Preparation, Structure, Photoluminescent and Semiconductive Properties

Chen

Cai

et al. 2018

Journal of Chemical Research

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A manganese complex with mixed ligands, [Mn(2,2′-biim)2(4,4′-bipy)] n[Mn(2,2′-biim)3]2 n6 n(ClO4)•8 nH2O (2,2′-biim = 2,2′-biimidazole; 4,4′-bipy = 4,4′-bipyridine), has been obtained by a hydrothermal procedure and its structure determined by single-crystal X-ray crystallography. A two-dimensional (2-D) supramolecular layer is established through hydrogen-bonding interactions. Solid-state photoluminescence measurement reveals that this complex shows a blue light emission. Solid-state diffuse reflectance determination uncovers the presence of a narrow optical band gap of 2.18 eV in this complex.

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ChemInform Abstract: MANGANESE (COORDINATION CHEMISTRY)

Crisp¹,

Seddon²

1981

Chemischer Informationsdienst

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Manganese

Cited by 6 publications

References 190 publications

Manganese Coordination Compounds: Classification and Analysis of Crystallographic and Structural Data

Manganese Coordination Compounds: Classification and Analysis of Crystallographic and Structural Data

A Novel Manganese Complex with Mixed Ligands: Preparation, Structure, Photoluminescent and Semiconductive Properties

ChemInform Abstract: MANGANESE (COORDINATION CHEMISTRY)

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