Magnetic Spinels - Synthesis, Properties and Applications 2017
DOI: 10.5772/66522
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Manganese-Zinc Spinel Ferrite Nanoparticles and Ferrofluids

Abstract: The nanoparticles and ferrofluids of spinel ferrites are useful in bio-sensors, transducers, storage devices, optical devices, and so on. The Mn-Zn ferrite (MZF) is generalized soft spinel ferrite having high saturation magnetization at low applied magnetic field. This chapter covers the synthesis of nanoparticles of various sizes and compositions of Mn 1-x Zn x Fe 2 O 4 with x = 0-1 by co-precipitation method. The structural and magnetic properties of the nanoparticles are discussed. The ferrofluids of superp… Show more

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Cited by 12 publications
(7 citation statements)
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“…The classic problem that causes difficulty in attaining stable ferrofluids is the tendency of Fe 3 O 4 to agglomerate as a result of van der Waals forces [18], which interfere with the single-domain formation of magnetic nanoparticles. Thus far, to solve such problems, extensive effort has been devoted to coating the fillers in ferrofluids with various surfactants, such as oleic acid [13], other carboxylic acids [19], and tetramethylammonium ion [20], using a monolayer technique. In principle, surfactants were subject to coat magnetic nanoparticle fillers so that they remain stable under an external magnetic field [21].…”
Section: Introductionmentioning
confidence: 99%
“…The classic problem that causes difficulty in attaining stable ferrofluids is the tendency of Fe 3 O 4 to agglomerate as a result of van der Waals forces [18], which interfere with the single-domain formation of magnetic nanoparticles. Thus far, to solve such problems, extensive effort has been devoted to coating the fillers in ferrofluids with various surfactants, such as oleic acid [13], other carboxylic acids [19], and tetramethylammonium ion [20], using a monolayer technique. In principle, surfactants were subject to coat magnetic nanoparticle fillers so that they remain stable under an external magnetic field [21].…”
Section: Introductionmentioning
confidence: 99%
“…Aside from ferrite nanoparticles, metal oxide nanoparticles have intrigued much attention due to their surface area to volume ratios and magnetic properties, which are wholly distinct from their corresponding bulk material. According to magnetic and crystal properties ferrites can be garnet, spinel, orthoferrite or hexaferrite [2][3][4][5]. Among them, ferrite nanoparticles synthesized with transition metal with spinel structure have been given special attention due to their well-known magnetic, catalytic, high adsorption, optical and electronic properties [6].…”
Section: Imentioning
confidence: 99%
“…Therefore, linear and nonlinear optical properties of ferrofluids based on manganese–zinc ferrite (Mn 0.5 Zn 0.5 Fe 2 O 4 ) nanoparticles, containing nanoparticles of spherical and cubic shapes, were studied studied in this work. Manganese–zinc ferrite nanoparticles compose a highly interesting system due to remarkable magnetic properties, as its low Curie temperature, high saturation magnetization at low applied magnetic field, as well as a high pyromagnetic coefficient, that is, the magnetization change rate depending on the temperature in the temperature range from 300 to 450 K. Therefore, since the system is interesting from the magnetic point of view, being suitable for applications as a coolant for transformers, the combination of optical measurements and magnetic properties of magnetic nanoparticles benefits from the special response due to the presence of static magnetic field. In addition, effects of external uniform magnetic fields over these properties were studied in order to characterize the NLO parameter anisotropy and the influence of the nanoparticle shape on the anisotropy magnitude.…”
Section: Introductionmentioning
confidence: 99%