The wave functions of a number of positron-atom complexes are analyzed and three of the systems, namely, e Be, e Na, and e He 3 S e , are seen to exhibit quantum halo structures with 45%-50% of their probability distribution lying in the large r classically forbidden region. The mean square distance between the large r fragments (e Be, Ps Na , Ps He ) for these systems range from 1.8 to 2.2 times larger than the square of the classical turning point, another indication of their halolike nature.