Influence of hydrostatic pressure on the light emission from strained GaN/AlGaN multi-quantumwell systems has been studied. Pressure coefficients of the photoluminescence peak energies show a strong reduction with respect to that of the GaN energy gap and this reduction is a function of the quantum-well thickness. The decrease of the light emission pressure coefficient may be almost 40% for a 32 monolayer (8 nm) thick quantum well in comparison with a 4 monolayer well. We explain this effect by a hydrostatic-pressure-induced increase of the piezoelectric field in the GaN/ AlGaN quantum structures.Introduction The contribution of the built-in electric field to the properties of wurtzite group-III nitrides has been widely disputed during the last few years [1-3]. Concerning experimental observations, the Quantum Confined Stark Effect (QCSE) and related peculiarities in the light emission from InGaN/GaN quantum wells (QWs) as well as high concentration carrier gases at undoped GaN/AlGaN heterostructures have been demonstrated. Spontaneous polarization and a huge piezoelectric field due to the large lattice/thermal expansion mismatch of the different nitride binary compounds lead to built-in electric fields, which can achieve a magnitude of few MV/cm.Another puzzling behavior of InGaN/GaN QWs consists in findings of anomalously low pressure coefficients of the photo-and electro-luminescence lines (dE/dp) [4]. dE/dp shows a dramatic decrease, which scales well with the decrease of E in variety of InGaN/GaN quantum structures. Since such a behavior suggests involvement of strongly localized states, it was tempting to associate it with In segregation in the InGaN QW. Such segregation results in narrowing of the InGaN alloy bandgap [5]. Accordingly, regions of high In content produce highly efficient radiative recombination which occurs due to strong localization of excitons/electron-hole pairs. However strong arguments against this interpretation have been supplied by Vaschenko et al. [6] who reported on the pressure induced increase of the photoluminescence decay time, t, in QWs of InGaN/GaN. This effect corresponds to the spatial separation of the wave functions of recombining electron and hole pairs due to the increase of a strong electric field (QCSE) in the studied structures. Moreover, a significant decrease of dE/dp accompanying the increase of t has been also found.