Mapping and classification of ionic liquids in terms of glass transition and fragility

Terashima, Yukio; Hirai, Taisuke

doi:10.1007/s10973-022-11427-z

Cited by 4 publications

(1 citation statement)

References 49 publications

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“…They range from moderately fragile 1-Methyl-3-octylimidazolium chloride with m = 39 to extremely fragile 1-Butyl-1-methypyrrolidinium bis(trifluoromethylsulfonyl)imide with m = 115. The glass transition temperature, heat capacity change at T g , and fragility index m of ionic glass-formers were found to be somehow related to the molar mass (M) of a material [ 113 ].…”

Section: Liquid Fragility Conceptmentioning

confidence: 99%

Structural Changes in Metallic Glass-Forming Liquids on Cooling and Subsequent Vitrification in Relationship with Their Properties

Louzguine‐Luzgin

2022

Materials

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The present review is related to the studies of structural changes observed in metallic glass-forming liquids on cooling and subsequent vitrification in terms of radial distribution function and its analogues. These structural changes are discussed in relationship with liquid’s properties, especially the relaxation time and viscosity. These changes are found to be directly responsible for liquid fragility: deviation of the temperature dependence of viscosity of a supercooled liquid from the Arrhenius equation through modification of the activation energy for viscous flow. Further studies of this phenomenon are necessary to provide direct mathematical correlation between the atomic structure and properties.

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Section: Liquid Fragility Conceptmentioning

confidence: 99%

Structural Changes in Metallic Glass-Forming Liquids on Cooling and Subsequent Vitrification in Relationship with Their Properties

Louzguine‐Luzgin

2022

Materials

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Non-Arrhenius Behavior of the Viscosity and Glass Transition of 1,2-Propanediol Solutions Containing LiBF4

Terashima

2023

J Solution Chem

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Fragility and glass transition of 1,2-propanediamine and 1,2-propanediol binary mixtures

Terashima,

Takeda

2024

J Therm Anal Calorim

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Mapping and classification of ionic liquids in terms of glass transition and fragility

Cited by 4 publications

References 49 publications

Structural Changes in Metallic Glass-Forming Liquids on Cooling and Subsequent Vitrification in Relationship with Their Properties

Structural Changes in Metallic Glass-Forming Liquids on Cooling and Subsequent Vitrification in Relationship with Their Properties

Non-Arrhenius Behavior of the Viscosity and Glass Transition of 1,2-Propanediol Solutions Containing LiBF4

Fragility and glass transition of 1,2-propanediamine and 1,2-propanediol binary mixtures

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