“…Gray and Jones 278 measured the rate constants of the reactions between CH 3 radicals and EA and its deuterated structure, but they reported that the activation energy at the N-H bond is 6.5 kcal mol À1 , lower than that at the a-C-H bond (8.1 kcal mol À1 ). Th : o and Sa ´ng 299 theoretically investigated the MEPs for the EA + CH 3 reaction, and the channel at the a-C-H bond was also identified as the most favorable channel.…”
Amines, as a class of prototypical volatile organic compounds, have garnered considerable interest within the atmospheric and combustion chemistry due to their substantial contributions to the formation of hazardous pollutants...
“…Gray and Jones 278 measured the rate constants of the reactions between CH 3 radicals and EA and its deuterated structure, but they reported that the activation energy at the N-H bond is 6.5 kcal mol À1 , lower than that at the a-C-H bond (8.1 kcal mol À1 ). Th : o and Sa ´ng 299 theoretically investigated the MEPs for the EA + CH 3 reaction, and the channel at the a-C-H bond was also identified as the most favorable channel.…”
Amines, as a class of prototypical volatile organic compounds, have garnered considerable interest within the atmospheric and combustion chemistry due to their substantial contributions to the formation of hazardous pollutants...
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