This study compares the effectiveness of different methods for coal thickness identification, aiming to identify the most accurate approach and provide a reference for intelligent coalmine development. Focused on the No. 2 coal seam in a mining area in Shanxi, China, the analysis employs well log-constrained impedance inversion and seismic multi-attribute techniques. The results show that the back propagation (BP) neural network model, as part of the seismic multi-attribute approach, delivers prediction accuracy comparable to the well log-constrained inversion method. Specifically, after applying proper static corrections, a four-layer BP neural network was constructed using four optimized sensitive attributes as the input layer, achieving an error range of 0.11% to 1.36%, compared to 0.03% to 6.59% for the logging-based method. The BP neural network demonstrated strong applicability in complex geological environments. Empirical analysis further validated the BP neural network’s geological reliability and practicality in systematic coal thickness determination.