The cross-section ratio for H(d, y)'He relative to H(d, a)n has been measured at an effective deuteron bombarding energy of 100 keV with a NaI pair spectrometer and a tritiated-titanium target. The ratio was determined to be (1.2+0.3) X 10 by comparing the spectra and count rates for H(d, y)'He and H(d, a)n with H( He, y )'Li and H( He, e)'H.