1997
DOI: 10.1016/s0168-583x(96)00460-0
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Mass spectra formation from charged microparticles

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Cited by 12 publications
(6 citation statements)
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“…This suggests a similar formation process, i.e., desorption. 40 This is consistent with the models of non-equilibrium desorption by Krueger 41 and Knabe. 34 In contrast to this study, the authors described the impact ionization process as generally comparable with laser ionization experiments.…”
Section: Mass Line Shapesupporting
confidence: 89%
“…This suggests a similar formation process, i.e., desorption. 40 This is consistent with the models of non-equilibrium desorption by Krueger 41 and Knabe. 34 In contrast to this study, the authors described the impact ionization process as generally comparable with laser ionization experiments.…”
Section: Mass Line Shapesupporting
confidence: 89%
“…The origins of hydrogen, carbon, and oxygen ions are not well understood, although such peaks have been frequently observed in impact ionization experiments by others [ Friichtenicht , 1964; Ratcliff and Allahdadi , 1996; Roy , 1975]. It is believed that they result from pump oil or adsorbed gases ionized by electron emission immediately prior to impact [ Austin et al , 2003; Novikov et al , 1988; Sysoev et al , 1992, 1997]. The peak at m/z = 27 could be C 2 H 3 + , as has been suggested from other impact experiments [ Ratcliff and Allahdadi , 1996], but could also be aluminum, which was used in constructing several parts of the instrument.…”
Section: Resultsmentioning
confidence: 99%
“…This behavior is more consistent with the parent species for higher velocity impacts being O rather than CH 4 or NH 2 , due to the high ionization energy of O. The low velocity appearance may be due to pre‐impact charge transfer [ Sysoev et al , 1997; McDonnell et al , 2001; Austin et al , 2003] generation of O ions, or the organic molecular candidates. The continued increase in the abundance of the 16 u peak with increasing impact velocity also indicates that the species is monatomic and abundant, as would be expected for a component of both the organic coating, contamination and the mineral.…”
Section: Discussionmentioning
confidence: 99%