Summary
Significant electrical resistance is observed in porous electrodes of microfluidic fuel cell due to the size limitation of this energy system. In this work, role of electrical resistance and geometry of porous electrodes in the performance of microfluidic fuel cells is studied with a three‐dimensional numerical model. Parametric simulations are performed to find proper ways to reduce the electrical resistance, including increasing the electrical conductivity of the electrode, changing the electrode geometry, and optimizing the current collector design. The results indicate that the cell cannot fully get rid of the negative influences of the electrical resistance by increasing the electrical conductivity due to the material restriction. Decreasing the electrode length or increasing the electrode width is also not feasible due to the trade‐off between current and current density. Optimization of the aspect ratio of the electrode active region is proved effective in realizing the enhancement of both current and current density. Extending the current collector area from the exposed end to the active region of the porous electrode is also promising as it can decrease the electrical resistance and boost the cell performance simultaneously. The present findings are generally applicable to various miniaturized fuel cell types using porous electrodes.