Two-dimensional
diamond, or diamane, is an ultrathin film with
unique physical properties that combine the record values of the bulk
crystal with the exciting features caused by the nanoscale nature.
At the current stage of research, the diamane properties are mostly
studied theoretically, and the main experimental efforts are directed
at its synthesis. The latter is the trickiest problem since traditional
methods involving the application
of high pressure are not fully suitable due to the influence of surface
effects. For diamane research, this poses a number of challenges,
whose description is the main purpose and scope of this review. The
paper also discusses the progress made so far and outlines the prospects
for this field, at the crossroads of the timeless diamond and decade-old
graphene.