Materials Design Strategies for Solvent-Resistant Organic Electronics

Abstract

Design of organic π-conjugated semiconducting materials is an exciting avenue of research that has already found promising applications in a wide variety of fields, ranging from stretchable electronics to bioimaging and theranostics. With favorable optoelectronic and thermomechanical properties, these materials and related devices can provide a complementary alternative to commercial silicon-based electronics. One of the most important features of organic semiconductors is their ability to be solution processed, allowing access to a wide variety of printing and solution deposition techniques inaccessible to silicon. However, the solution processability of these materials also poses challenges for the development of multilayer electronics due to potential problems such as swelling, film deformation and interfacial mixing that can occur upon successive solution deposition. Use of orthogonal (noncompatible) solvents and solvent-free deposition methods have been extensively investigated as solutions to this challenge, although the applicability of these approaches is limited by the chemical properties of the materials used. Another approach to address this problem is to focus on the materials rather than deposition methods. Through rational design, functional groups can be used to create triggered solvent resistance through covalent or dynamic intermolecular bonds. Design strategies include the incorporation of photo- and thermally cleavable functional groups in the materials, or the use of chemical additives/reagents to significantly alter the solubility of π-conjugated materials and afford solvent-resistant thin films. This spotlight article presents recent progress toward solvent-resistant organic materials with an emphasis on their use in electronic applications. Recent and key developments will be discussed from a personal perspective, providing an overview of the different approaches used to achieve solvent-resistant semiconducting materials toward the fabrication of advanced, multilayer organic electronics.

All slot-die coated organic solar cells using an amine processed cathode interlayer based upon an amino acid functionalised perylene bisimide

“…When designing solvent-resistant films, it is common for a post-treatment stage to be used postdeposition to generate this resistance. 42 Such methods require either putting energy into the system using heat 43 or UV light 44 or by using chemical reagents. 45 However, here we present a way to make solvent resistant and uniform films without the need for such treatment.…”

Synthesis, structural, and photophysical properties of pyrazolyl bis(pentafluorophenyl)boron complexes

“…The study of organic luminescent materials has evolved into an important topic owing to their potential applications in organic lasers, photoswitches and organic electronics. 1 Different strategies have been employed to tune the electronic and, photophysical properties, stability, and durability of such materials. 2 Attractive photophysical properties were achieved by incorporating main-group elements in the framework of organic molecules.…”