2007
DOI: 10.1002/ppap.200600148
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Materials Science and Technological Aspects of Electrospark Deposition of Nanostructured WC‐Co Coatings onto Titanium Substrates

Abstract: The composition and structure of coatings deposited with nano‐ and microstructured electrodes WC‐8% Co onto Ti substrates were characterized by XRD, XPS, EPMA, SEM, and SIM. Physical and chemical processes taking place at the contact surface of electrode and substrate during electrospark deposition are considered. Under optimized conditions (E = 0.13 J), deposition with a nanostructured electrodes provides fine‐grained coatings exhibiting higher hardness, improved wear resistance, and a lower friction coeffici… Show more

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Cited by 26 publications
(24 citation statements)
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“…With an increase in the pulse energy, an increase in the diameter and time of the spark discharge occurs, as a result of which the erosion of the electrodes increases. The depth and size of the craters of the solidified material on the cathode grows and, as a result, the roughness increases [6][7][8][9][14][15]. In the ESD of the samples with initial roughness Ra=1.67, 2.5 and 3 μm, the roughness Ra of the coatings of all used electrodes at pulse energy up to 0.03 J is close to that of the initial titanium surface (Fig.…”
Section: J)mentioning
confidence: 91%
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“…With an increase in the pulse energy, an increase in the diameter and time of the spark discharge occurs, as a result of which the erosion of the electrodes increases. The depth and size of the craters of the solidified material on the cathode grows and, as a result, the roughness increases [6][7][8][9][14][15]. In the ESD of the samples with initial roughness Ra=1.67, 2.5 and 3 μm, the roughness Ra of the coatings of all used electrodes at pulse energy up to 0.03 J is close to that of the initial titanium surface (Fig.…”
Section: J)mentioning
confidence: 91%
“…The ESD surface layer changes the friction conditions in two main directions: a change of surface composition, the structure, and the surface microgeometry change. It is known that most often after ESD the roughness of the coatings is higher than that of the base and the relatively high roughness of ESD coatings adversely affects the wear resistance of coated products [6][7][8][9][10][11][12][13][14][15][16][17][18][19][20][21][22][23][24][25].…”
Section: Introductionmentioning
confidence: 99%
“…The grain size of WC in these electrodes was 1–2 µm and the residual porosity below 0.1 vol.‐%. The structures of both electrode materials were documented in a previous publication 4…”
Section: Experimental Partmentioning
confidence: 99%
“…Tungsten carbidebased hard alloys with cobalt binders have become widespread as electrode materials for the fabrication of coatings [4][5][6][7][8]. However, these electrode materials have a high erosion resistance and transfer poorly to the cathode.…”
Section: Introductionmentioning
confidence: 99%